Calculation of thermodynamic properties of liquid Fe-Ln alloys

Authors

  • Natalia Vladimirovna Kotova Taras Shevchenko National University of Kyiv
  • Natalia Valerievna Golovata Taras Shevchenko National University of Kyiv
  • Natalia Igorevna Usenko Taras Shevchenko National University of Kyiv

DOI:

https://doi.org/10.17721/fujcV3I2P40-43

Keywords:

liquid alloys, iron, lanthanides, thermodynamic properties calculation, “surrounded atom” model

Abstract

This paper presents the results of estimation of thermodynamic properties of binary Fe–Ln systems which characterized by small or moderate energy of component interaction in liquid state. The good agreement between enthalpies of mixing calculated in “surrounded atom” approximation and experimentally obtained enthalpies of mixing is observed for all investigated systems including Fe–Pr one, in which sign variable values of heat effects were determined. The method of estimation of excess Gibbs energies of liquid Fe–Ln alloys is proposed and the results of such estimation are given for a number of systems including those experimentally unexplored yet.

References

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Published

2015-10-27

Issue

Vol. 3 No. 2 (2015): Proceedings of the VIII International scientific conference “Kiev-Toulouse”

Section

Articles

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