NEW 3-(2-PYRIDYL)-1,2,4-TRIAZOLE DERIVATIVES AND THEIR PALLADIUM (II) COMPLEXES

Authors

  • Borys V. Zakharchenko Department of Chemistry, Taras Shevchenko National University of Kyiv, Volodymyrska Street, 64/13, Kyiv 01033, Ukraine
  • Dmytro M. Khomenko Department of Chemistry, Taras Shevchenko National University of Kyiv, Volodymyrska Street, 64/13, Kyiv 01033, Ukraine
  • Roman O. Doroschuk Department of Chemistry, Taras Shevchenko National University of Kyiv, Volodymyrska Street, 64/13, Kyiv 01033, Ukraine
  • Rostyslav D. Lampeka Department of Chemistry, Taras Shevchenko National University of Kyiv, Volodymyrska Street, 64/13, Kyiv 01033, Ukraine

DOI:

https://doi.org/10.17721/fujcV3I2P115-118

Keywords:

palladium, triazole, coordination compound, NMR-spectroscopy

Abstract

The article is devoted to investigation of coordination compounds of palladium (II) with 3-(2-pyridyl)-1,2,4-triazole derivatives containing amino groups. We syntesized 4 ligands and 4 new coordination compounds. An interesting after removing of BOC-protection, NH2-group is still uncoordinated. In 1H NMR spectra of complexes was a significant shift of the ortho-pyridine proton in a low-field area, which prove proposed structure. This may be due to its closeness to the lone electron pair of the nitrogen cycle of the second triazole ligand.

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Published

2015-12-29

Issue

Vol. 3 No. 2 (2015): Proceedings of the VIII International scientific conference “Kiev-Toulouse”

Section

Articles

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