New chiral bis(oxazolinyl)bipyridine ligands and application in the iron catalyzed asymmetric hydrosilylation of ketones
DOI:
https://doi.org/10.17721/fujcV3I2P44-53Keywords:
chiral bisoxazoline, bipyridine, hydrosilylation, iron, ketonesAbstract
C2 symmetrical 6,6′-bis(oxazolinyl)-2,2′-bipyridine (bipybox) chiral ligands have been synthesized from readily available 2,2′-bipyridine. Catalytic asymmetric hydrosilylation of ketones was studied using this family of ligands in the presence of iron(II) acetate.
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