New Ferrocene Derivatives for Ligand Grafting

Authors

  • Andrii Karpus Université Toulouse III - Paul Sabatier, 118 route de Narbonne 31062 Toulouse Cedex 9 Laboratoire de Chimie de Coordination du CNRS, 205 route de Narbonne, 31077 Toulouse cedex 4 Taras Shevchenko National University of Kyiv, 64/13 Volodymyrska st., Kyiv 01601, Ukraine
  • Jean-Claude Daran Université Toulouse III - Paul Sabatier, 118 route de Narbonne 31062 Toulouse Cedex 9 Laboratoire de Chimie de Coordination du CNRS, 205 route de Narbonne, 31077 Toulouse cedex 4
  • Zoia Voitenko Taras Shevchenko National University of Kyiv, 64/13 Volodymyrska st., Kyiv 01601, Ukraine
  • Eric Manoury Université Toulouse III - Paul Sabatier, 118 route de Narbonne 31062 Toulouse Cedex 9 Laboratoire de Chimie de Coordination du CNRS, 205 route de Narbonne, 31077 Toulouse cedex 4

DOI:

https://doi.org/10.17721/fujcV3I2P131-139

Keywords:

ferrocene, grafting, P, N ligands, O ligands

Abstract

Five new 1,2-disubstituted ferrocene derivatives have been efficiently synthesized. These compounds contain one protected phosphine function as thiophosphine, another coordination site (nitrogen or oxygen atom) and a function ready for the grafting on various supports. All compounds have been and fully characterized by NMR(1H, 31P and 13C)  and High Resolution Mass Spectroscopy. The molecular structure of three of these ferrocene derivatives have been determined by X ray diffraction analysis on monocrystals.

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Published

2016-02-27